Glass: The Old, The New, The Natural

What is glass, how is it made by humans and in nature and what are its uses?

Computer Screen and desk (2014-11-03)Original Source: Wikimedia Commons

We use glass every day, from looking through a window, to drinking from a cup, to using a phone screen to view this page. Glass is made by humans but is also made in nature during powerful events like lightning strikes, volcanic eruptions and extra-terrestrial impacts.

What is glass?

Glass is made by melting pure quartz sand, grains of which are made of silicon dioxide, also known as silica. Glass and quartz are made of the same material but they do not have the same molecular structure. In natural quartz the molecules of silicon dioxide are arranged in a regular pattern. Molten glass is cooled quickly so the silicon dioxide molecules are arranged randomly; this characteristic of glass affects how it behaves and is used.

Quartz, From the collection of: Geoscience Australia
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History of glass making

The Egyptian’s were the first to create a glazed glass layer on ceramic vessels as early as 3500 BCE. Glass making began about 3300 BCE, at the start of the Bronze age, and glass was traded across Egypt, Mycenaean Greece and Mesopotamia (modern day Iraq and surrounding regions). In 100 BCE Syrian craftsman developed the first pipe for blowing glass which allowed glass vessels to be made more quickly and easily and less expensively.

Glass vessel in the form of a pomegranate, -1340/-1200, From the collection of: British Museum
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Compound Microscope and Case (about 1751) by Michel-Ferdinand d'Albert d'Ailly, 6th duke of Chaulnes and Jacques CaffieriThe J. Paul Getty Museum

Glass and technology

The ability to make and shape glass allowed many technological and scientific advances such as production of lenses used in telescopes and microscopes; in turn these instruments enabled advances in our understandings of astronomy and biology.

Silica sand Silica sandGeoscience Australia

Challenges in making glass

One of the biggest challenges glass makers have to overcome is the high melting point of silica at 1710 degrees Celsius.

By creating the right combination of silica and other ingredients (known as fluxes) the temperature needed to melt the silica is reduced, which in turn reduces the cost, time and energy required to make glass.

Glassblowing in Rogaška glassworks by Iztok NikolićSlovenian Tourist Board

The addition of specific compounds during the glass making process gives glass unique physical characteristics like colour or degree of heat resistance.

By Andreas FeiningerLIFE Photo Collection

Soda-lime glass

Soda-lime glass is used to make clear glass objects like cups, containers and windows; it is made by adding soda (sodium compound) and lime (calcium compound) to silica. The soda acts as a flux agent, lowering the melting temperature and the lime is a stabilizing agent. 

By Andreas FeiningerLIFE Photo Collection

Borosilicate glass

The other main type of glass is borosilicate glass which has a boron compound like borax added to make it more resistant to thermal changes. Borosilicate glass is mainly used to make scientific glassware and oven proof glass like Pyrex®.

Dragonfly Hanging Lamp (c. 1906) by Clara DriscollThe Museum of Fine Arts, Houston

Coloured glass

To make different coloured glass specific powdered metal oxides or metal sulphides are added.

‘Clear’ glass often has some iron impurities within its structure that gives it a slight green tinge. Small amounts of manganese oxide is added as a decolouriser to counteract the green tones and was used as early as 200 BCE. If a higher concentration of manganese oxide is added to a mix, it creates a pale purple coloured glass.

Bottle, Unknown, 20. Jahrhundert, From the collection of: Pergamonmuseum, Staatliche Museen zu Berlin
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In 2000 BCE cobalt oxide was used in Egypt to create a dark blue coloured glass. It gained popularity during this time because the blue glass was similar in appearance to the highly valued gemstone lapis lazuli.

Krateriskos, Unknown, about 1403–1347 B.C., From the collection of: The J. Paul Getty Museum
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Lapis Lazuli, From the collection of: Geoscience Australia
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Lightning over white mountains (2017-05-12)Original Source: Wikimedia Commons

Natural glass

Not all glass is made by humans; several forms of glass are made by natural processes like lightning strikes, volcanic eruptions and meteorite impacts.

FulguriteGeoscience Australia

Glass created by lightning

When lightning strikes quartz sand, such as in a beach or desert, fulgurites (specifically lechatelerite) are created. The high temperature at the exact place where the lightning strikes causes the sand to melt rapidly and form glass, often in a tubular shape.

Some fulgurites have an elongated shape that tracks the path of the lightning through the sand.

FulguriteGeoscience Australia

It is believed that the centre of a fulgurite is hollow because the sand in the centre is completely vaporised by the lightning strike.

FulguriteGeoscience Australia

As the newly made glass begins to cool, sand particles often fuse with the sticky molten glass to create the rough texture on the outside of fulgurites.

Uses for fulgurites

Scientists are studying the properties of fulgurites to collect information about the lightning strikes that create them. This will help them better understand the energy needed for this process to occur as well as how the amount of energy varies as lightning passes through the sand. Fulgurites have even been used for forensic work in legal cases to determine if a fire was caused by power lines or a lightning strike.

Tolbachik Volcano by ePP

Glass created by volcanoes

Obsidian (volcanic glass) is dark-coloured natural glass formed by the rapid cooling of silica-rich lava. As the lava is erupted from a volcano, it cools so rapidly that only glass and some microscopic crystals can form. These microcrystals create a black or dark green colour.

Obsidian is not chemically stable in the long term. Over time, parts of the randomly arranged glassy rock rearrange into regular patterns, creating a quartz-type mineral called cristobalite. This change in structure is known as devitrification. When polished these white inclusions in the obsidian look like snowflakes in the black rock, so this is called ‘snowflake obsidian’

Snowflake Obsidian and Obsidian, From the collection of: Geoscience Australia
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ObsidianGeoscience Australia

When obsidian is broken the fresh surfaces are smooth with curved patterns on them, as seen in the picture. These conchoidal fractures have sharp edges and mean that obsidian can be shaped to make very sharp tools.

Uses for obsidian

Obsidian has and continues to be used by Indigenous people around the world for many different purposes. Obsidian was used by the Rapa Nui people as part of the eye design for the Easter Island heads called Moai. Pre-Columbian Mesoamericans used obsidian for decorations, in trade and, most commonly, to make tools and weapons.

Obsidian spear points (reproduction), From the collection of: Geoscience Australia
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Obsidian tools were first used as medical blades in Egypt and Turkey during the Bronze age. Modern surgeons use medical grade steel scalpels for surgery but some doctors prefer an obsidian bladed scalpel; they have a sharper edge than steel and do not leave any trace metals in a wound. Obsidian scalpels are also much cheaper than other specialty scalpels (like diamond scalpels), however, they are much more fragile and require special care to prevent them breaking.

Obsidian blade, ca. 2700–2200 B.C., From the collection of: The Metropolitan Museum of Art
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TektitesGeoscience Australia

Glass created by meteorite impacts

When meteorites impact the Earth they can create natural glass in the form of impact glass and tektites.

The force of a large meteorite hitting the ground can cause the surrounding rock to melt due to heat, pressure, or shock-waves. If this melted rock cools rapidly then glass can form, and if this glass remains around the impact site it is called impact glass or impactite.

Some meteorites cause the rock at the impact site to not only melt but also the molten blobs are splashed high up into the atmosphere, sometimes even into space. When this molten material falls back through the atmosphere to Earth ‘tektites’ are created.

Darwin GlassGeoscience Australia

Darwin Glass

In Australia, impact glass is found near Mt Darwin in Tasmania and is called Darwin glass. It was formed when a meteorite impacted Tasmania approximately 800,000 years ago. 

The molten material rapidly cooled as it was ejected from the impact site creating irregular shaped pieces with gas bubble inclusions. Darwin glass ranges in colour from light green to dark brown-green.

Darwin GlassGeoscience Australia

Uses for Darwin Glass

As far back as 27,000 years ago, First Nations Australians in Tasmania used Darwin glass to make sharp-edged tools. There is evidence of Darwin glass, and the tools created from it, being traded in Tasmania 170 km north of the original impact site.

Tektites TektitesGeoscience Australia

Australites

Tektites found in Australia are known as Australites. It is believed they formed 790,000 years ago due to a major meteorite impact in Southern Laos. 

AustraliteGeoscience Australia

The key feature of some Australites is their button-like shapes. When they re-entered the atmosphere, the bottom of the glass pieces started to melt, pressure pushed the molten material upwards during the descent and created a ripple effect on the sides. 

AustraliteGeoscience Australia

Uses for Australites

NASA even studied the shape of Australites for the Apollo program. By designing their re-entry spacecrafts to be a similar shape, NASA was able to create more aerodynamic structures that ensured a safer re-entry and return to Earth for their command modules.

Natural and human-made glass is all around us and has been used for thousands of years to better all our lives.

You can test your knowledge from viewing this exhibit by completing the 'Glass Crossword' on the Geoscience Australia website.

Credits: Story

Glass making and glass blowing (Glassworks Canberra)
Coloured glass (African Pegmatite)
History of glass (Knowable)
History of glass
History of surgical scalpel (Qlick Smart)
Obsidian (New World Encyclopedia)
Origin of Darwin Glass (Kieren Torres Howard , University of Tasmania)
Silicon dioxide properties (PubChem)
Australites (McColl, Don. (2017). Australia's Little Space Travellers. 1st ed. Springer Cham).
Australites (Melosh, Jay. (2020). The Australasian tektite source crater: Found at last?. Proceedings of the National Academy of Sciences. 117. 201920576. 10.1073/pnas.1920576117).
Fulgurites (Pasek, M. A. and Hurst, M.(2016). A Fossilized Energy Distribution of Lightning. Sci. Rep. 6, 30586; doi: 10.1038/srep30586)
The National Mineral and Commonwealth Paleontological Collection, Geoscience Australia and The National Museum of Australia Mineral Collections (specimens)

Tamara Sullivan, Joe Fayle, Shona Blewett (text/editing)
Steven Petkovski,  Rod Kennett (reviews)

Credits: All media
The story featured may in some cases have been created by an independent third party and may not always represent the views of the institutions, listed below, who have supplied the content.

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